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Summary

Description
English: Diffusion from a microscopic and macroscopic point of view. Initially, there are solute molecules on the left side of a barrier (magenta line) and none on the right. The barrier is removed, and the solute diffuses to fill the whole container. Top: A single molecule moves around randomly. Middle: With more molecules, there is a clear trend where the solute fills the container more and more evenly. Bottom: With an enormous number of solute molecules, the randomness is gone: The solute appears to move smoothly and systematically from high-concentration areas to low-concentration areas, following Fick's laws. Image is made in Mathematica, source code below.
Date
Source Own work
Author Sbyrnes321

Licensing

Public domain I, the copyright holder of this work, release this work into the public domain. This applies worldwide.
In some countries this may not be legally possible; if so:
I grant anyone the right to use this work for any purpose, without any conditions, unless such conditions are required by law.

<< Mathematica source code >>

(* Source code written in Mathematica 6.0, by Steve Byrnes, 2010.
I release this code into the public domain. Sorry it's messy...email me any questions. *)

(*Particle simulation*)
SeedRandom[1];
NumParticles = 70;
xMax = 0.7;
yMax = 0.2;
xStartMax = 0.5;
StepDist = 0.04;
InitParticleCoordinates = Table[{RandomReal[{0, xStartMax}], RandomReal[{0, yMax}]}, {i, 1, NumParticles}];
StayInBoxX[x_] := If[x < 0, -x, If[x > xMax, 2 xMax - x, x]];
StayInBoxY[y_] := If[y < 0, -y, If[y > yMax, 2 yMax - y, y]];
StayInBoxXY[xy_] := {StayInBoxX[xy[[1]]], StayInBoxY[xy[[2]]]};
StayInBarX[x_] := If[x < 0, -x, If[x > xStartMax, 2 xStartMax - x, x]];
StayInBarY[y_] := If[y < 0, -y, If[y > yMax, 2 yMax - y, y]];
StayInBarXY[xy_] := {StayInBarX[xy[[1]]], StayInBarY[xy[[2]]]};
MoveAStep[xy_] := StayInBoxXY[xy + {RandomReal[{-StepDist, StepDist}], RandomReal[{-StepDist, StepDist}]}];
MoveAStepBar[xy_] := StayInBarXY[xy + {RandomReal[{-StepDist, StepDist}], RandomReal[{-StepDist, StepDist}]}];
NextParticleCoordinates[ParticleCoords_] := MoveAStep /@ ParticleCoords;
NextParticleCoordinatesBar[ParticleCoords_] := MoveAStepBar /@ ParticleCoords;
NumFramesBarrier = 10;
NumFramesNoBarrier = 50;
NumFrames = NumFramesBarrier + NumFramesNoBarrier;
ParticleCoordinatesTable = Table[0, {i, 1, NumFrames}];
ParticleCoordinatesTable[[1]] = InitParticleCoordinates;
For[i = 2, i <= NumFrames, i++,
  If[i <= NumFramesBarrier,
   ParticleCoordinatesTable[[i]] = NextParticleCoordinatesBar[ParticleCoordinatesTable[[i - 1]]], 
   ParticleCoordinatesTable[[i]] = NextParticleCoordinates[ParticleCoordinatesTable[[i - 1]]]];];

(*Plot full particle simulation*)
makeplotbar[ParticleCoord_] := 
  ListPlot[{ParticleCoord, {{xStartMax, 0}, {xStartMax, yMax}}}, Frame -> True, Axes -> False,
   PlotRange -> {{0, xMax}, {0, yMax}}, Joined -> {False, True}, PlotStyle -> {PointSize[.03], Thick},
   AspectRatio -> yMax/xMax, FrameTicks -> None];

makeplot[ParticleCoord_] := 
 ListPlot[ParticleCoord, Frame -> True, Axes -> False, PlotRange -> {{0, xMax}, {0, yMax}}, Joined -> False, 
  PlotStyle -> PointSize[.03], AspectRatio -> yMax/xMax, FrameTicks -> None]

ParticlesPlots = 
  Join[Table[makeplotbar[ParticleCoordinatesTable[[i]]], {i, 1, NumFramesBarrier}], 
   Table[makeplot[ParticleCoordinatesTable[[i]]], {i, NumFramesBarrier + 1, NumFrames}]];

(*Plot just the first particle in the list...Actually the fifth particle looks better. *) 
FirstParticleTable = {#[[5]]} & /@ ParticleCoordinatesTable;

FirstParticlePlots = 
  Join[Table[makeplotbar[FirstParticleTable[[i]]], {i, 1, NumFramesBarrier}], 
   Table[makeplot[FirstParticleTable[[i]]], {i, NumFramesBarrier + 1, NumFrames}]];


(* Continuum solution *)

(* I can use the simple diffusion-on-an-infinite-line formula, as long as I correctly periodically replicate the
initial condition. Actually just computed nearest five replicas in each direction, that was a fine approximation. *)

(* k = diffusion coefficient, visually matched to simulation. *)
k = .0007; 
u[x_, t_] := If[t == 0, If[x <= xStartMax, 1, 0], 1/2 Sum[
     Erf[(x - (-xStartMax + 2 n xMax))/Sqrt[4 k t]] - Erf[(x - (xStartMax + 2 n xMax))/Sqrt[4 k t]], {n, -5, 5}]];

ContinuumPlots = Join[
   Table[Show[
     DensityPlot[1 - u[x, 0], {x, 0, xMax}, {y, 0, yMax}, 
      ColorFunctionScaling -> False, AspectRatio -> yMax/xMax, 
      FrameTicks -> None],
     ListPlot[{{xStartMax, 0}, {xStartMax, yMax}}, Joined -> True, 
      PlotStyle -> {Thick, Purple}]],
    {i, 1, NumFramesBarrier}],
   Table[
    DensityPlot[1 - u[x, tt], {x, 0, xMax}, {y, 0, yMax}, 
     ColorFunctionScaling -> False, AspectRatio -> yMax/xMax, 
     FrameTicks -> None],
    {tt, 1, NumFramesNoBarrier}]];

(*Combine and export *)

TogetherPlots = 
  Table[GraphicsGrid[{{FirstParticlePlots[[i]]}, {ParticlesPlots[[i]]}, {ContinuumPlots[[i]]}},
   Spacings -> Scaled[0.2]], {i, 1, NumFrames}];

Export["test.gif", Join[TogetherPlots, Table[Graphics[], {i, 1, 5}]], 
 "DisplayDurations" -> {10}, "AnimationRepititions" -> Infinity ]

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depicts English

creator English

Some value without a Wikidata item

inception English

16 January 2010

media type English

image/gif

data size English

411,139 byte

height English

300 pixel

width English

360 pixel

checksum English

4a8949cf448ee06c9385f339d7c15689f0a5b187

Historial de l'image

Puncha en la data/hora per a vore l'image tal i com es mostrava en eixe moment.

Data/HoraMiniaturaDimensionsUsuariDescripció
actual13:41 7 març 2012Miniatura de la versió de 13:41 7 març 2012360 × 300 (402 kB)wikimediacommons>Dratini0Just removed the white last fram for aesthetic purposes, and prologed the display time of the last frame to mark the reatart of the animation.

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